Journal of Agriculture ›› 2020, Vol. 10 ›› Issue (11): 48-52.doi: 10.11923/j.issn.2095-4050.cjas20191000215
Previous Articles Next Articles
Lv Liang1(), Ma Pan2(), Gong Shaoyan3
Received:
2019-10-12
Revised:
2019-12-18
Online:
2020-11-20
Published:
2020-11-18
Contact:
Ma Pan
E-mail:xiaoliang1227@163.com
CLC Number:
Lv Liang, Ma Pan, Gong Shaoyan. The Determination of Exchangeable Ca and Mg in Soil by ICP-OES[J]. Journal of Agriculture, 2020, 10(11): 48-52.
Add to citation manager EndNote|Ris|BibTeX
URL: http://nxxb.caass.org.cn/EN/10.11923/j.issn.2095-4050.cjas20191000215
平行号 | 钙 | 镁 | |
---|---|---|---|
测定结果/ (mg/kg) | 1 | 0.0123 | 0.0086 |
2 | 0.0122 | 0.0087 | |
3 | 0.0124 | 0.0089 | |
4 | 0.0123 | 0.0085 | |
5 | 0.0126 | 0.0086 | |
6 | 0.0124 | 0.0087 | |
7 | 0.0120 | 0.0084 | |
平均值x/(mg/kg) | 0.0123 | 0.0086 | |
标准偏差S | 0.0151 | 0.0186 | |
t值 | 3.143 | 3.143 | |
检出限/(mg/kg) | 0.0474 | 0.0584 | |
测定下限/(mg/kg) | 0.1898 | 0.2338 |
平行号 | 钙 | 镁 | |
---|---|---|---|
测定结果/ (mg/kg) | 1 | 0.0123 | 0.0086 |
2 | 0.0122 | 0.0087 | |
3 | 0.0124 | 0.0089 | |
4 | 0.0123 | 0.0085 | |
5 | 0.0126 | 0.0086 | |
6 | 0.0124 | 0.0087 | |
7 | 0.0120 | 0.0084 | |
平均值x/(mg/kg) | 0.0123 | 0.0086 | |
标准偏差S | 0.0151 | 0.0186 | |
t值 | 3.143 | 3.143 | |
检出限/(mg/kg) | 0.0474 | 0.0584 | |
测定下限/(mg/kg) | 0.1898 | 0.2338 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.59 | 3.8 | 1.21 | 17.9 | 4.27 | 12.9 | 3.91 | |||
2 | 14.2 | 3.46 | 4.0 | 1.23 | 18.3 | 4.33 | 13.1 | 3.93 | |||
3 | 14.0 | 3.52 | 3.9 | 1.22 | 18.1 | 4.30 | 13.0 | 3.92 | |||
4 | 14.8 | 3.69 | 4.6 | 1.24 | 17.5 | 4.40 | 13.2 | 3.99 | |||
5 | 14.0 | 3.42 | 4.3 | 1.17 | 18.3 | 4.21 | 13.4 | 3.95 | |||
6 | 14.4 | 3.49 | 4.5 | 1.15 | 18.5 | 4.35 | 13.2 | 4.01 | |||
7 | 14.2 | 3.45 | 4.4 | 1.16 | 18.4 | 4.28 | 13.3 | 3.98 | |||
8 | 14.3 | 3.53 | 4.5 | 1.12 | 17.9 | 4.27 | 12.7 | 4.02 | |||
9 | 13.9 | 3.55 | 4.1 | 1.19 | 17.2 | 4.36 | 13.0 | 4.08 | |||
10 | 13.8 | 3.47 | 3.9 | 1.29 | 17.9 | 4.33 | 13.1 | 4.01 | |||
11 | 14.6 | 3.65 | 3.8 | 1.19 | 18.0 | 4.37 | 12.8 | 3.92 | |||
平均值 | 14.2 | 3.53 | 4.2 | 1.20 | 18.0 | 4.32 | 13.1 | 3.97 | |||
RSD/% | 2.29 | 2.42 | 7.31 | 3.97 | 2.16 | 1.28 | 1.62 | 1.35 | |||
标准值(参考值)(X±s) | 14.4±1.5 | 3.54±0.24 | 4.2±0.8 | 1.21±0.12 | 17.8±1.0 | 4.3±0.2 | 13.0±1.6 | 3.98±0.14 | |||
测定值与标准值相对误差/% | 1.41 | 0.28 | 0.00 | 0.83 | 1.12 | 4.65 | 0.77 | 0.25 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.59 | 3.8 | 1.21 | 17.9 | 4.27 | 12.9 | 3.91 | |||
2 | 14.2 | 3.46 | 4.0 | 1.23 | 18.3 | 4.33 | 13.1 | 3.93 | |||
3 | 14.0 | 3.52 | 3.9 | 1.22 | 18.1 | 4.30 | 13.0 | 3.92 | |||
4 | 14.8 | 3.69 | 4.6 | 1.24 | 17.5 | 4.40 | 13.2 | 3.99 | |||
5 | 14.0 | 3.42 | 4.3 | 1.17 | 18.3 | 4.21 | 13.4 | 3.95 | |||
6 | 14.4 | 3.49 | 4.5 | 1.15 | 18.5 | 4.35 | 13.2 | 4.01 | |||
7 | 14.2 | 3.45 | 4.4 | 1.16 | 18.4 | 4.28 | 13.3 | 3.98 | |||
8 | 14.3 | 3.53 | 4.5 | 1.12 | 17.9 | 4.27 | 12.7 | 4.02 | |||
9 | 13.9 | 3.55 | 4.1 | 1.19 | 17.2 | 4.36 | 13.0 | 4.08 | |||
10 | 13.8 | 3.47 | 3.9 | 1.29 | 17.9 | 4.33 | 13.1 | 4.01 | |||
11 | 14.6 | 3.65 | 3.8 | 1.19 | 18.0 | 4.37 | 12.8 | 3.92 | |||
平均值 | 14.2 | 3.53 | 4.2 | 1.20 | 18.0 | 4.32 | 13.1 | 3.97 | |||
RSD/% | 2.29 | 2.42 | 7.31 | 3.97 | 2.16 | 1.28 | 1.62 | 1.35 | |||
标准值(参考值)(X±s) | 14.4±1.5 | 3.54±0.24 | 4.2±0.8 | 1.21±0.12 | 17.8±1.0 | 4.3±0.2 | 13.0±1.6 | 3.98±0.14 | |||
测定值与标准值相对误差/% | 1.41 | 0.28 | 0.00 | 0.83 | 1.12 | 4.65 | 0.77 | 0.25 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.59 | 3.8 | 1.21 | 17.9 | 4.27 | 12.9 | 3.91 | |||
2 | 14.2 | 3.46 | 4.0 | 1.23 | 18.3 | 4.33 | 13.1 | 3.93 | |||
3 | 14.0 | 3.52 | 3.9 | 1.22 | 18.1 | 4.30 | 13.0 | 3.92 | |||
4 | 14.8 | 3.69 | 4.2 | 1.24 | 17.5 | 4.40 | 13.2 | 3.99 | |||
5 | 14.0 | 3.42 | 4.3 | 1.17 | 18.3 | 4.21 | 13.4 | 3.95 | |||
6 | 14.4 | 3.49 | 4.5 | 1.15 | 18.5 | 4.35 | 13.2 | 4.01 | |||
7 | 14.2 | 3.45 | 4.4 | 1.16 | 18.4 | 4.28 | 13.3 | 3.98 | |||
8 | 14.3 | 3.53 | 4.5 | 1.12 | 17.9 | 4.27 | 12.7 | 4.02 | |||
9 | 13.9 | 3.55 | 4.1 | 1.19 | 17.2 | 4.36 | 13.0 | 4.08 | |||
10 | 13.8 | 3.47 | 3.9 | 1.29 | 17.9 | 4.33 | 13.1 | 4.01 | |||
11 | 14.6 | 3.65 | 3.8 | 1.19 | 18.0 | 4.37 | 12.8 | 3.92 | |||
平均值 | 14.2 | 3.53 | 4.2 | 1.20 | 18. | 4.32 | 13.1 | 3.97 | |||
RSD/% | 2.29 | 2.42 | 4.31 | 3.97 | 2.16 | 1.28 | 1.62 | 1.35 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.59 | 3.8 | 1.21 | 17.9 | 4.27 | 12.9 | 3.91 | |||
2 | 14.2 | 3.46 | 4.0 | 1.23 | 18.3 | 4.33 | 13.1 | 3.93 | |||
3 | 14.0 | 3.52 | 3.9 | 1.22 | 18.1 | 4.30 | 13.0 | 3.92 | |||
4 | 14.8 | 3.69 | 4.2 | 1.24 | 17.5 | 4.40 | 13.2 | 3.99 | |||
5 | 14.0 | 3.42 | 4.3 | 1.17 | 18.3 | 4.21 | 13.4 | 3.95 | |||
6 | 14.4 | 3.49 | 4.5 | 1.15 | 18.5 | 4.35 | 13.2 | 4.01 | |||
7 | 14.2 | 3.45 | 4.4 | 1.16 | 18.4 | 4.28 | 13.3 | 3.98 | |||
8 | 14.3 | 3.53 | 4.5 | 1.12 | 17.9 | 4.27 | 12.7 | 4.02 | |||
9 | 13.9 | 3.55 | 4.1 | 1.19 | 17.2 | 4.36 | 13.0 | 4.08 | |||
10 | 13.8 | 3.47 | 3.9 | 1.29 | 17.9 | 4.33 | 13.1 | 4.01 | |||
11 | 14.6 | 3.65 | 3.8 | 1.19 | 18.0 | 4.37 | 12.8 | 3.92 | |||
平均值 | 14.2 | 3.53 | 4.2 | 1.20 | 18. | 4.32 | 13.1 | 3.97 | |||
RSD/% | 2.29 | 2.42 | 4.31 | 3.97 | 2.16 | 1.28 | 1.62 | 1.35 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.60 | 3.9 | 1.19 | 17.5 | 4.25 | 12.9 | 3.94 | |||
2 | 13.7 | 3.42 | 3.9 | 1.23 | 18.1 | 4.31 | 13.1 | 3.91 | |||
3 | 13.9 | 3.39 | 4.2 | 1.27 | 17.9 | 4.19 | 13.0 | 4.01 | |||
4 | 13.9 | 3.47 | 4.1 | 1.18 | 18.3 | 4.33 | 13.2 | 4.03 | |||
5 | 13.7 | 3.53 | 4.0 | 1.30 | 17.5 | 4.27 | 12.8 | 3.99 | |||
6 | 14.0 | 3.62 | 4.2 | 1.24 | 17.6 | 4.26 | 12.7 | 4.00 | |||
7 | 14.3 | 3.70 | 3.8 | 1.26 | 17.8 | 4.21 | 13.1 | 3.97 | |||
8 | 14.0 | 3.49 | 4.0 | 1.20 | 18.1 | 4.29 | 13.0 | 3.96 | |||
平均值 | 13.9 | 3.53 | 4.0 | 1.23 | 17.8 | 4.26 | 13.0 | 3.98 | |||
最大相对相差/% | 4.32 | 4.82 | 7.50 | 9.76 | 4.49 | 2.82 | 3.85 | 3.01 |
测定次数 | GBW07412 | GBW07416 | ASA-1a | ASA-4a | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
1 | 13.8 | 3.60 | 3.9 | 1.19 | 17.5 | 4.25 | 12.9 | 3.94 | |||
2 | 13.7 | 3.42 | 3.9 | 1.23 | 18.1 | 4.31 | 13.1 | 3.91 | |||
3 | 13.9 | 3.39 | 4.2 | 1.27 | 17.9 | 4.19 | 13.0 | 4.01 | |||
4 | 13.9 | 3.47 | 4.1 | 1.18 | 18.3 | 4.33 | 13.2 | 4.03 | |||
5 | 13.7 | 3.53 | 4.0 | 1.30 | 17.5 | 4.27 | 12.8 | 3.99 | |||
6 | 14.0 | 3.62 | 4.2 | 1.24 | 17.6 | 4.26 | 12.7 | 4.00 | |||
7 | 14.3 | 3.70 | 3.8 | 1.26 | 17.8 | 4.21 | 13.1 | 3.97 | |||
8 | 14.0 | 3.49 | 4.0 | 1.20 | 18.1 | 4.29 | 13.0 | 3.96 | |||
平均值 | 13.9 | 3.53 | 4.0 | 1.23 | 17.8 | 4.26 | 13.0 | 3.98 | |||
最大相对相差/% | 4.32 | 4.82 | 7.50 | 9.76 | 4.49 | 2.82 | 3.85 | 3.01 |
土样编号 | 标准值及不确定度 | 人员1 | 人员2 | 人员3 | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
ASA-1a | 17.8±1.0 | 4.3±0.2 | 17.6 | 4.21 | 18.3 | 4.19 | 18.2 | 4.42 | |||
ASA-4a | 13.0±0.6 | 3.98±0.14 | 12.9 | 3.89 | 13.4 | 3.97 | 13.3 | 4.06 | |||
GBW07412 | 14.4±1.5 | 3.54±0.24 | 13.8 | 3.43 | 14.9 | 3.67 | 14.7 | 3.52 | |||
GBW07416 | 4.2±0.8 | 1.21±0.12 | 3.9 | 1.19 | 4.3 | 1.23 | 4.1 | 1.27 |
土样编号 | 标准值及不确定度 | 人员1 | 人员2 | 人员3 | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | Ca2+ | Mg2+ | ||||
ASA-1a | 17.8±1.0 | 4.3±0.2 | 17.6 | 4.21 | 18.3 | 4.19 | 18.2 | 4.42 | |||
ASA-4a | 13.0±0.6 | 3.98±0.14 | 12.9 | 3.89 | 13.4 | 3.97 | 13.3 | 4.06 | |||
GBW07412 | 14.4±1.5 | 3.54±0.24 | 13.8 | 3.43 | 14.9 | 3.67 | 14.7 | 3.52 | |||
GBW07416 | 4.2±0.8 | 1.21±0.12 | 3.9 | 1.19 | 4.3 | 1.23 | 4.1 | 1.27 |
[1] | 王忠. 植物生理学[M]. 北京: 中国农业出版社, 1999: 187-261. |
[2] | 陆景陵. 植物营养学(第2版)[M]. 北京: 中国农业大学出版社, 2003: 65-72. |
[3] | 熊英杰, 陈少风, 李恩香, 等. Research Progress and Outlook on Magnesium Deficiency in Plants[J]. Journal of Anhui Agricultural Sciences, 2010,38(15):7754-7757. |
[4] | 刘长景, 王春雷, 李凤. 平衡施肥防治蔬菜缺素症研究综述[J]. China Fruit and Vegetable, 2008,( 5):33. |
[5] | 劳家柽主编. 土壤农化分析手册[M]. 北京: 农业出版社, 1988: 317. |
[6] | 土壤分析技术规范(第二版)[M]. 北京: 农业出版社, 2006. |
[7] | GB 7865-87,森林土壤中交换性钙和镁的测定[S]. |
[8] | LY/T 1245—1999森林土壤交换性钙和镁的测定[S]. |
[9] | NY/T 1121.13—2006土壤检测第13部分:土壤交换性钙和镁的测定[S]. |
[10] | 辛仁轩. 等离子体发射光谱分析[M]. 北京: 化学工业出版社, 2005: 152. |
[11] | 周建英, 涂明泉, 熊玉祥, 等. ICP-AES法同时测定土壤中交换性钙、镁、钾和钠[J]. 资源环境与工程, 2007(8):486-488. |
[12] | 杨乐苏. ICP-AES直接测定土壤中多种交换性阳离子组成[J]. 广东林业科技, 2008,24(6):20-23. |
[13] | 吴雪莲, 邱诚. 等离子体发射光谱仪测定西藏土壤矿质元素前处理方法研究[J]. 现代仪器, 2012,18(3):94-97. |
[14] | 姜勇, 张玉革. 耕地土壤交换性钙镁比值的研究[J]. 土壤通报, 2003,10, 34(5):414-417. |
[15] | 许自成, 黎妍妍, 肖汉乾, 等. 湖南烟区土壤交换性钙、镁含量及对烤烟品质的影响[J]. 生态学报, 2007,27(11):4425-4433. |
[16] | Wang D S, XU Q K, Wang N R, et al. Content of Median and Trace Elements in Soil ofTobaccoPlantingRegions in Jiangxi Province[J]. Guizhou Agricultural Sciences, 2011,39(2):91-96. |
[17] | 李丹, 陈水森. 近红外光谱预测土壤钾、钙、镁与阳离子交换量研究[J]. 热带地理, 2011,7(31):368-372. |
[18] | 杨乐苏, 于彬, 王志香. 南方酸性土壤交换性钙、镁和钾测定方法的探讨[J]. Tropical Forestry, 2005,33:21-22. |
[19] | 胡建新, 汪莹. 攀枝花烟区土壤交换性钙、镁含量平价[J]. 西南农业学报, 2011,24(4):1415-1418. |
[20] | 刘雪鸿, 王京平, 陈万明, 等. 酸性、中性土壤交换性钙镁测定方法的探讨[J]. 湖南农业科学, 2004(3):26-27. |
[21] | 冯建军, 陈丽芝, 张玉珠. 酸性土壤交换性钙、镁测定方法的探讨[J]. 内蒙古农业科技, 2008(5):76-77. |
[22] | Jiang L L, Li X H, Wang C, et al. Method Improvement for Determining Exchangeable Calcium and Exchangeable Magnesium in Soil[J]. Hunan Agricultural Sciences, 2011(5):41-43,47. |
[23] | Chen J G, Zhang Y Z, Zeng X B, et al. Effects of Long-term Various Fertilization on exchangeable Ca and Mg,and available S and Si Contents in Paddy soils[J]. Ecology and Environmnet, 2008,17(5):2064-2067. |
[24] | 魏林根, 李建国, 苏全平, 等. 振荡浸提—原子吸收光谱法测定土壤中交换性钙镁[J]. 分析测试技术与仪器, 2006,12(4):249-252. |
[25] | 张白鸽, 陈琼贤, 曹健, 等. 珠三角主菜区土壤交换性钙、镁的丰缺指标及分布特征[J]. 华南农业大学学报, 2011,32(2):25-29. |
[1] | ZHANG Jian, ZHANG Mingkui. Heterogeneity of Available Phosphorus in Regional Farmland Soil and Its Causes [J]. Journal of Agriculture, 2022, 12(8): 43-47. |
[2] | GUO Shanhu, ZHOU Zonggui, LIU Min, PAN Wenzheng, ZHANG Lifang, ZHAO Xuetong, ZHANG Qi, XIAO Yongfei. Effects of Soil Improvement Materials on Physicochemical Properties of Soil and Yield and Quality of Flue-cured Tobacco [J]. Journal of Agriculture, 2022, 12(8): 62-67. |
[3] | YAN Jianli, ZHANG Mingkui, WANG Daoze. Improvement Effect of Combined Application of Phosphogypsum and Limestone Powder on Newly Cultivated Red Soil [J]. Journal of Agriculture, 2022, 12(7): 33-37. |
[4] | SUN Bin, ZHANG Jiajia, SONG Yujiao, HAI Fei, WANG Lei. 5% Prohexadione Calcium EA: Effects on Lodging Resistance, Yield and Its Related Factors of Wheat [J]. Journal of Agriculture, 2022, 12(6): 14-17. |
[5] | LI Xiaoyan. Barrier Analysis of Greenhouse Soil and Effect of Balanced Fertilizer Application [J]. Journal of Agriculture, 2022, 12(6): 39-43. |
[6] | WANG Yuanyuan. Terrain Factors Related to Hydrology in the Loess Plateau of Northern Shaanxi Based on DEM [J]. Journal of Agriculture, 2022, 12(5): 17-23. |
[7] | LIAO Feifei, LIU Xinggui, WANG Kexiu, DU Yongli, XIONG Hu, ZHANG Deyin. Gibberellin and Foliar Fertilizer: Effects on Pre-basic Seeds of Potato Production by Aeroponics [J]. Journal of Agriculture, 2022, 12(4): 18-23. |
[8] | ZHAO Shaoting, LI Jianmin, DU Yu. Form and Valence Evaluation of Heavy Metal Chromium in Soil: A Review [J]. Journal of Agriculture, 2022, 12(4): 24-28. |
[9] | LI Wenqing, ZHENG Chaoyuan, KE Yuqin, CHEN Shunhui, GUO Jinping, LI Chunying. Effects of Magnesium Fertilizer Application on Soil Magnesium Supply and Growth and Development, Yield and Quality of Flue-cured Tobacco [J]. Journal of Agriculture, 2022, 12(4): 33-40. |
[10] | CONG Xiaofeng, CHEN Hao, LI Weimin, LI Dan, LI Sifeng. Habitat Investigation and Rhizosphere Soil Analysis of Wild Fritillaria taibaiensis [J]. Journal of Agriculture, 2022, 12(3): 55-58. |
[11] | WANG Binqiang, HE Shaolang, LIN Xiaobing, ZHANG Kun, WANG Xinyue, HUANG Shangshu, CHENG Yanhong, HUANG Qianru. Soil Nutrient Status and Its Correlation with Root Dry Weight of Pueraria thomsonii Benth in Jiangxi [J]. Journal of Agriculture, 2022, 12(2): 26-30. |
[12] | GUO Zhenwei, LI Yongshan, CHEN Mengni, FAN Qiaolan, WANG Hui. Effects of Cotton Straw Returning on Cotton Growth and Soil: Research Progress [J]. Journal of Agriculture, 2022, 12(12): 18-22. |
[13] | GU Huizhan, GOU Xiaomei, CAI Yan, WU Jie, LI Tao, YE Xiang, HE Jiexuan, ZHANG Qili, WANG Dong. Effects of Tobacco-Rape Rotation and Balanced Fertilization on Soil Available Potassium and Potassium in Tobacco Leaves [J]. Journal of Agriculture, 2022, 12(12): 23-27. |
[14] | XUE Zhiwei, HUANG Qingqing, YANG Chunling. Heavy Metal Content of Soil and Wheat Seeds Around Anyang: Correlation and Principal Component Analysis [J]. Journal of Agriculture, 2022, 12(12): 28-33. |
[15] | QIU Yao, TAN Shiyong, WEN Yaxiong, XU Xuewen. Organic Fertilizer Has Great Potential in the Goal of ‘Peaking Carbon Emissions and Achieving Carbon Neutrality’ [J]. Journal of Agriculture, 2022, 12(12): 34-39. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||