Journal of Agriculture ›› 2021, Vol. 11 ›› Issue (10): 95-101.doi: 10.11923/j.issn.2095-4050.cjas20190600065
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Weng Jia(), Huang Xiuli, Zhu Wenjuan, Wang Xiaoqin
Received:
2019-06-03
Revised:
2019-10-08
Online:
2021-10-20
Published:
2021-10-28
CLC Number:
Weng Jia, Huang Xiuli, Zhu Wenjuan, Wang Xiaoqin. Application of Triglyceride Fingerprint in Identification of Adulterated Edible Oil[J]. Journal of Agriculture, 2021, 11(10): 95-101.
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URL: http://nxxb.caass.org.cn/EN/10.11923/j.issn.2095-4050.cjas20190600065
精密度 | 重复性 | 稳定性 | 加标回收 | ||||
---|---|---|---|---|---|---|---|
对照品连续进样 6针峰面积 | RSD/ % | 平行6份样品的 含量/% | RSD/ % | 样品放置1~6 h的含量/ % | RSD/ % | 6份样品 回收率/% | 平均回收率/ % |
1550560 | 0.4 | 15.13 | 1.3 | 15.52 | 0.4 | 101.10 | 101.4 |
1552735 | 15.32 | 15.48 | 103.25 | ||||
1558359 | 15.42 | 15.59 | 102.68 | ||||
1558727 | 15.66 | 15.45 | 98.74 | ||||
1544298 | 15.50 | 15.52 | 102.37 | ||||
1545139 | 15.23 | 15.39 | 100.52 |
精密度 | 重复性 | 稳定性 | 加标回收 | ||||
---|---|---|---|---|---|---|---|
对照品连续进样 6针峰面积 | RSD/ % | 平行6份样品的 含量/% | RSD/ % | 样品放置1~6 h的含量/ % | RSD/ % | 6份样品 回收率/% | 平均回收率/ % |
1550560 | 0.4 | 15.13 | 1.3 | 15.52 | 0.4 | 101.10 | 101.4 |
1552735 | 15.32 | 15.48 | 103.25 | ||||
1558359 | 15.42 | 15.59 | 102.68 | ||||
1558727 | 15.66 | 15.45 | 98.74 | ||||
1544298 | 15.50 | 15.52 | 102.37 | ||||
1545139 | 15.23 | 15.39 | 100.52 |
菜籽油 | 大豆油 | 玉米油 | 葵花籽油 | 花生油 | 橄榄油 | |
---|---|---|---|---|---|---|
菜籽油 | 1.000 | 0.333 | 0.529 | 0.303 | 0.894 | 0.830 |
大豆油 | 0.333 | 1.000 | 0.937 | 0.933 | 0.535 | 0.086 |
玉米油 | 0.529 | 0.937 | 1.000 | 0.917 | 0.728 | 0.233 |
葵花籽油 | 0.303 | 0.933 | 0.917 | 1.000 | 0.526 | 0.073 |
花生油 | 0.894 | 0.535 | 0.728 | 0.526 | 1.000 | 0.776 |
橄榄油 | 0.830 | 0.086 | 0.233 | 0.073 | 0.776 | 1.000 |
菜籽油 | 大豆油 | 玉米油 | 葵花籽油 | 花生油 | 橄榄油 | |
---|---|---|---|---|---|---|
菜籽油 | 1.000 | 0.333 | 0.529 | 0.303 | 0.894 | 0.830 |
大豆油 | 0.333 | 1.000 | 0.937 | 0.933 | 0.535 | 0.086 |
玉米油 | 0.529 | 0.937 | 1.000 | 0.917 | 0.728 | 0.233 |
葵花籽油 | 0.303 | 0.933 | 0.917 | 1.000 | 0.526 | 0.073 |
花生油 | 0.894 | 0.535 | 0.728 | 0.526 | 1.000 | 0.776 |
橄榄油 | 0.830 | 0.086 | 0.233 | 0.073 | 0.776 | 1.000 |
菜籽油掺入 比例/% | 与橄榄油 相似度 | 大豆油掺入 比例/% | 与橄榄油 相似度 | 玉米油掺入 比例/% | 与橄榄油 相似度 | 葵花籽油油掺入比例/% | 与橄榄油 相似度 |
---|---|---|---|---|---|---|---|
10 | 1.000 | 10 | 1.000 | 10 | 0.999 | 10 | 1.000 |
20 | 0.999 | 20 | 0.999 | 20 | 0.999 | 20 | 0.994 |
40 | 0.994 | 40 | 0.983 | 40 | 0.956 | 40 | 0.933 |
60 | 0.978 | 60 | 0.879 | 60 | 0.761 | 60 | 0.699 |
80 | 0.940 | 80 | 0.501 | 80 | 0.385 | 80 | 0.327 |
菜籽油掺入 比例/% | 与橄榄油 相似度 | 大豆油掺入 比例/% | 与橄榄油 相似度 | 玉米油掺入 比例/% | 与橄榄油 相似度 | 葵花籽油油掺入比例/% | 与橄榄油 相似度 |
---|---|---|---|---|---|---|---|
10 | 1.000 | 10 | 1.000 | 10 | 0.999 | 10 | 1.000 |
20 | 0.999 | 20 | 0.999 | 20 | 0.999 | 20 | 0.994 |
40 | 0.994 | 40 | 0.983 | 40 | 0.956 | 40 | 0.933 |
60 | 0.978 | 60 | 0.879 | 60 | 0.761 | 60 | 0.699 |
80 | 0.940 | 80 | 0.501 | 80 | 0.385 | 80 | 0.327 |
菜籽油掺入 比例/% | 与橄榄油 相似度 | 大豆油掺入 比例/% | 与橄榄油 相似度 | 玉米油掺入 比例/% | 与橄榄油 相似度 | 葵花籽油油掺入比例/% | 与橄榄油 相似度 |
---|---|---|---|---|---|---|---|
10 | 0.996 | 10 | 0.814 | 10 | 0.706 | 10 | 0.887 |
20 | 0.972 | 20 | 0.750 | 20 | 0.825 | 20 | 0.645 |
40 | 0.916 | 40 | 0.708 | 40 | 0.753 | 40 | 0.632 |
60 | 0.934 | 60 | 0.698 | 60 | 0.744 | 60 | 0.655 |
80 | 0.917 | 80 | 0.695 | 80 | 0.744 | 80 | 0.626 |
菜籽油掺入 比例/% | 与橄榄油 相似度 | 大豆油掺入 比例/% | 与橄榄油 相似度 | 玉米油掺入 比例/% | 与橄榄油 相似度 | 葵花籽油油掺入比例/% | 与橄榄油 相似度 |
---|---|---|---|---|---|---|---|
10 | 0.996 | 10 | 0.814 | 10 | 0.706 | 10 | 0.887 |
20 | 0.972 | 20 | 0.750 | 20 | 0.825 | 20 | 0.645 |
40 | 0.916 | 40 | 0.708 | 40 | 0.753 | 40 | 0.632 |
60 | 0.934 | 60 | 0.698 | 60 | 0.744 | 60 | 0.655 |
80 | 0.917 | 80 | 0.695 | 80 | 0.744 | 80 | 0.626 |
特征峰1 | 特征峰2 | 特征峰3 | 特征峰4 | 特征峰5 | 特征峰6 | 特征峰7 | 特征峰8 | 特征峰9 | 特征峰10 | 特征峰11 | 特征峰12 | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
菜籽油 | - | - | 4.41 | 4.16 | 7.19 | 32.18 | 2.36 | 45.35 | 3.46 | - | 0.89 | - |
大豆油 | 8.83 | 25.82 | 1.19 | 23.56 | 15.21 | 8.42 | 12.03 | 1.24 | 3.28 | 0.42 | - | - |
橄榄油 | - | - | - | 0.18 | 0.19 | 7.98 | 1.22 | 62.78 | 22.69 | 0.68 | 4.07 | 0.21 |
花生油 | - | 4.67 | - | 18.61 | 3.58 | 20.54 | 11.04 | 30.42 | 8.81 | 0.40 | 1.82 | 0.11 |
葵花籽油 | - | 34.79 | - | 37.02 | 7.96 | 8.59 | 7.66 | 2.26 | 1.39 | 0.10 | 0.21 | - |
玉米油 | - | 19.73 | - | 26.72 | 14.48 | 16.75 | 11.66 | 6.89 | 3.25 | 0.27 | 0.24 | - |
特征峰1 | 特征峰2 | 特征峰3 | 特征峰4 | 特征峰5 | 特征峰6 | 特征峰7 | 特征峰8 | 特征峰9 | 特征峰10 | 特征峰11 | 特征峰12 | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
菜籽油 | - | - | 4.41 | 4.16 | 7.19 | 32.18 | 2.36 | 45.35 | 3.46 | - | 0.89 | - |
大豆油 | 8.83 | 25.82 | 1.19 | 23.56 | 15.21 | 8.42 | 12.03 | 1.24 | 3.28 | 0.42 | - | - |
橄榄油 | - | - | - | 0.18 | 0.19 | 7.98 | 1.22 | 62.78 | 22.69 | 0.68 | 4.07 | 0.21 |
花生油 | - | 4.67 | - | 18.61 | 3.58 | 20.54 | 11.04 | 30.42 | 8.81 | 0.40 | 1.82 | 0.11 |
葵花籽油 | - | 34.79 | - | 37.02 | 7.96 | 8.59 | 7.66 | 2.26 | 1.39 | 0.10 | 0.21 | - |
玉米油 | - | 19.73 | - | 26.72 | 14.48 | 16.75 | 11.66 | 6.89 | 3.25 | 0.27 | 0.24 | - |
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