Form and Valence Evaluation of Heavy Metal Chromium in Soil: A Review

doi:10.11923/j.issn.2095-4050.cjas2020-0284

Abstract

Abstract:

Soil environmental quality standards in China have established the limit for total chromium content in soil. To understand the effects of heavy metal chromium on ecological environment and soil organism, it is necessary to analyze different forms and valences of chromium in detail. In this study, the occurrence form, and the migration and transformation of heavy metal chromium in soil were discussed, especially the determination methods of different forms and valences of chromium. Sequential extraction method is still the main method for form analysis of chromium in soil. Compared with the solid-liquid extraction method and the technology of chromium separation, enrichment and determination based on soil liquid samples, direct solid sample analysis does not require sample pretreatment and avoids the form transformation of the element. In the future, more rapid and simple methods for determining heavy metals in soil will be developed.

Key words: soil, heavy metal, chromium, form, valence, migration and transformation, determination method

CLC Number:

ZHAO Shaoting, LI Jianmin, DU Yu. Form and Valence Evaluation of Heavy Metal Chromium in Soil: A Review[J]. Journal of Agriculture, 2022, 12(4): 24-28.

Figures/Tables 1

References 36

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萃取剂的选择	铬的形态
水	水溶态的Cr(VI)和Cr(III)
KCl溶液	总Cr(VI)
磷酸盐缓冲液(pH=7)	交换态的Cr(VI)
NaOH/Na₂CO₃稀溶液	总Cr(VI)
Na₂CO₃0.28 mol/L + NaOH 0.5 mol/L	总Cr(VI)
EDTA 50 mmol/L (pH=10)^[18]	总Cr(VI)和可溶态的Cr(III)

萃取剂的选择	铬的形态
水	水溶态的Cr(VI)和Cr(III)
KCl溶液	总Cr(VI)
磷酸盐缓冲液(pH=7)	交换态的Cr(VI)
NaOH/Na₂CO₃稀溶液	总Cr(VI)
Na₂CO₃0.28 mol/L + NaOH 0.5 mol/L	总Cr(VI)
EDTA 50 mmol/L (pH=10)^[18]	总Cr(VI)和可溶态的Cr(III)